Expanding the Scope of Metal-Free Catalytic Hydrogenation through Frustrated Lewis Pair Design

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Expanding the Scope of Metal-Free Catalytic Hydrogenation through Frustrated Lewis Pair Design

No metal causes frustration: Based on a conceptual framework, novel frustrated Lewis acid-base catalyst systems with orthogonal reactivity have been developed. Aside from enhanced functional-group tolerance, unique chemoselectivity can be achieved in catalytic metal-free hydrogenations (see scheme).

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